Organic Chemistry

Organic Chemistry, 6E......Page 3
Contents......Page 5
Preface......Page 23
Acknowledgments......Page 27
PART I - The Fundamentals......Page 28
1. Structure and Properties.......Page 29
2. Methane. Energy of Activation. Transition State.......Page 67
3. Alkanes. Free-Radical Substitution.......Page 101
 4. Stereochemistry I. Stereoisomers.......Page 143
5. Alkenes I. Structure and Preparation. Elimination.......Page 171
6. Alkenes II. Reactions of the Carbon-Carbon Double Bond. Electrophilic and Free-Radical Addition.......Page 205
7. Stereochemistry II. Preparation and Reactions of Stereoisomers......Page 253
8. Alkenes and Dienes......Page 276
9. Alicyclic Hydrocarbons......Page 309
10. Benzene. Aromatic Character......Page 344
11. Electrophilic Aromatic Substitution......Page 363
12. Arenes......Page 398
13. Spectroscopy amd Structure......Page 431
14. Alkyl Halides. Nucleophilic Aliphatic Substitution. Elimination......Page 478
15. Alcohols I. Preparation and Physical Properties......Page 518
16. Alcohols II. Reactions.......Page 544
17. Ethers and Epoxides......Page 578
18. Carboxylic Acids......Page 605
19. Aldehydes and Ketones. Nucleophilic Addition......Page 643
20. Functional Derivatives of Carboxylic Acids. Nucleophilic Acyl Substitution......Page 684
21. Carbanions I. Aldol and Claisen Condensations......Page 727
22. Amines I. Preparation and Physical Properties......Page 753
23. Amines II. Reactions......Page 771
24. Phenols......Page 813
PART II - Special Topics......Page 841
25. Aryl Halides. Nucleophilic Aromatic Substituiton......Page 843
26. Carbanions II. Malonic Ester and Acetoacetic Ester Synthesis......Page 872
27. alpha,beta-Unsaturated Carbonyl Compounds. Conjugate Addition......Page 891
28. Rearrangements and Neighboring Group Effects. Nonclassical Ions......Page 911
29. Molecular Orbitals. Orbital Symmetry......Page 951
30. Polynuclear Aromatic Compounds......Page 993
31. Heterocyclic Compounds......Page 1028
32. Macromolecules, Polymers and Polymerization......Page 1053
Part III - Biomolecules......Page 1079
33. Fats......Page 1081
34. Carbohydrates I. Monosaccharides......Page 1096
35. Carbohydrates II. Disaccharides and Polysaccharides......Page 1138
36. Amino Acids and Proteins......Page 1158
37. Biochemical Processes. Molecular Biology......Page 1190
Suggested Readings......Page 1211
Answers to Problems......Page 1219
Index......Page 1237